Parametric study on acid hydrolysis of Kapok (Ceiba pentandra (L.) Gaertn.) fibers for cellulose nanocrystals production

Date

12-2015

Degree

Bachelor of Science in Chemical Engineering

Major Course

Major in Pulp and Paper Technology

College

College of Engineering and Agro-Industrial Technology (CEAT)

Adviser/Committee Chair

Ronniel D. Manalo

Restrictions

Restricted: Not available to the general public. Access is available only after consultation with author/thesis adviser and only to those bound by the confidentiality agreement.

Abstract

The study dealt on the potential of Ceiba pentandra (L.) Gaertn. fibers as a source of cellulose nanocrystals (CNC). The fibers were pre-treated with chloroform and hot water to remove the extratives. Holocellulose and alpha-cellulose were then produced using 20% (w/v) sodium chlorite and 17.5% (w/v) sodium hydroxide, respectively. Cellulose nanocrystals were then isolated through acid hydrolysis by varying the sulfuric acid concentration (46% v/v and 50% v/v), reaction time (30 min and 45 min), and temperature (40° C and 50° C). The effects of the different combinations of the parameters on the yield were determined. Morphological characteristics of the CNC were observed using Atomic Force Microscopy (AFM). Chemical transformations of raw kapok to cellulose nanocrystals were analyzed using Fourier Transform Infrared Spectroscopy (FT-IR). From the results of the experiment, it was found out that the treatment combination of 46% acid concentration, 45 min, and 50 ° C gave the highest yield of 53.64% among the samples. Results of the spectroscropic analysis indicate that CNCs were obtained from kapok. Results of the AFM revealed that the average length and width of CNC with the highest yield were 105.50 nm and 27.22 nm, respectively. Using statistical analysis, it was found out that only temperature had a significant effect on the yield, while acid concentraion significantly affected the CNC length, on the other hand, CNC width was significantly affected by both reaction time and acid concentration.

Language

English

Location

UPLB College of Engineering and Agro-Industrial Technology (CEAT)

Call Number

LG 993.5 2015 E62 /V37

Document Type

Thesis

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